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Homochiral tricarbonyl chromium arenes in the stereoselective synthesis of heterocyclic compounds
Clara Baldoli,
Paola Del Buttero
and Stefano Maiorana
Dipartimento di Chimica Organica e Industriale dell'Universita' e Centro CNR, Università degli Studi di Milano, Via C. Golgi,19 -20133, Milano, Italy
Intermolecular [2+2] cycloaddition
Synthesis of homochiral 3-amino azetidin-2-one
Background
Resolution of
ortho
-substituted benzaldehydes
Reaction conditions
Products
Hypothesis for stereoselection
Intramolecular hetero-Diels-Alder reaction
Synthesis of homochiral
cis-
fused dihydropyran
Background
Resolution of
ortho
-substituted benzaldehydes
Synthesis of homochiral tricarbonyl chromium-2-(3-methylbut-2-enyloxy)benzaldehyde
Reaction conditions
Hypothesis of the transition state
