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2.1 Synthesis of the chiral triethanolamine:
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Chiral Silatranes
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1. Introduction
2. Experimental
Figure 2:
Synthesis of the chiral silatrane
2.1 Synthesis of the chiral triethanolamine: (1
R
,2
S
)-2-
N,N-bis(2-hydroxyethyl)-aminomethyl
-6,6-dimethyl-2-hydroxybicyclo
3.1.1
heptane
2.2 Synthesis of the methylsilatrane: (1
R
,2
S
)-1',6,6-trimethyl-spiro
bicyclo
3.1.1
heptane-2,3'-5-aza-2,8,9-trioxa-1-silabicyclo
3.3.3
undecane
Bjoern Pedersen
1998-06-22