Photochemical Generation of Mononuclear Complexes.

A wide number of mononuclear complexes have been prepared by photochemistry.

Work has focused on the synthesis of [eta]2-olefin complexes such as Ru(CO)4([eta]2-C2H4), prepared by broad-band UV photolysis of a solution of Ru3(CO)12 under an atmosphere of ethene.


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