R CO2Et C(OEt)=SO2CH3 Yields*(%) d.e.(%) Yields*(%) d.e.(%) H 62 75 CH3 33 16 54 20 CH2OCH3 54 8 22 8 (CH2)4 43 25 Ph 13 51 10 26*Inspection of 13C NMR spectra of crude reaction mixtures shows a complete conversion of acetals into aziridines. Almost all diastereomers can be easily separated by HPLC and it was possible to obtain single compounds with optical purity of nearly 100%.