An article entitled "Four Decades of the Chemistry of Planar Hypercoordinate Compounds"[cite]10.1002/anie.201410407[/cite] was recently reviewed by Steve Bacharach on his blog, where you can also see comments. Given the recent crystallographic themes here, I thought I might try a search of the CSD (Cambridge structure database) to see whether anything interesting might emerge for tetracoordinate carbon.
Posts Tagged ‘search results’
The conformational preference of s-cis amides.
Sunday, February 10th, 2013Amides with an H-N group are a component of the peptide linkage (O=C-NH). Here I ask what the conformation (it could also be called a configuration) about the C-N bond is. A search of the following type can be defined: