Table Of Contents

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  1. Abstract

  2. Acknoledgments

  3. Introduction

    1. Theoretical background

      1. Kinetics and thermodynamics

      2. Computational methods

      3. Transition States

    2. The Diels-Alder Reaction

  1. Study of some Diels-Alder Reactions

    1. The endo/exo selectivity

      1. Introduction : Diels-Alder addition of two cyclopentadienes

      2. Exo selectivity of the Diels-Alder addition of cyclopropenone and 1-3-diphenylisobenzofuran

      3. Semi-Empirical modelization of a Diels-Alder addition catalysed by a cyclic porphyrin trimer

    2. Reactions on destabilized aromatic rings

      1. TrisBicyclo[2.1.1]HexaBenzene

      2. Addition of a dienophile

      3. Addition of a diene

      4. Measure of the lost of aromaticity

  2. Structural dependencies of hydrogen bonds in methylcarbonyl and derived groups

    1. Introduction

    2. Statistical method

    3. Carbonyl

    4. Other groups

  3. Experimental

  4. References

  5. List of hyperactive molecules